After downloading the Cite While You Write plugin (under the Format tab in EndNote Basic), EndNote commands will appear in Word. The Cite While You Write plugin allows communication between EndNote Basic and Microsoft Word.
EndNote Basic (Web) in MS Word (2010) Toolbar
Use the "Cite While You Write" Plug-in to automatically insert references, format citations, and format bibliographies while you write your paper in Word.
This tutorial from Endnote, demonstrates how to add citations to a Word document.
Web of Science. "EndNote Online: Cite While You Write Overview ." Online video clip.
YouTube. YouTube, 27 June. 2014. Web. 30 June. 2014.